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CHEM20140

Academic Year 2024/2025

Introductory Transition Metal Chemistry (CHEM20140)

Subject:
Chemistry
College:
Science
School:
Chemistry
Level:
2 (Intermediate)
Credits:
5
Module Coordinator:
Assoc Professor Tony Keene
Trimester:
Spring
Mode of Delivery:
On Campus
Internship Module:
No
How will I be graded?
Letter grades

Curricular information is subject to change.

This course is an introduction to transition metal chemistry, examining the formation, shape, and properties of metal-ligand complexes. Recent literature complements fundamental background in the subject along with examples from industrial and research chemistry. This material gives an insight into macroscopic properties such as colour, reactivity and magnetic properties of transition metal complexes as a result of crystal field considerations. Topics covered include: Atomic structure and orbitals; Prediction of molecular geometry; Molecular orbital theory for simple diatomics; Symmetry elements and point groups; Lewis acids and bases; Metal-ligand bonding and coordination; Coordination geometry and conformation; Chelate and macrocyclic effects; Crystal field theory.
The laboratory component reinforces the above topics and provides instruction in the synthesis and characterisation of coordination complexes and the use of coordination complexes in analytical techniques.
Learning is reinforced by small group tutorial sessions and practice questions.

About this Module

Learning Outcomes:

On completion of this module, students are expected to:
- understand the nature of and predict the shape of atomic orbitals from the fundamental quantum numbers
- understand and predict the nature of bonding interactions in diatomics using molecular orbital theory
- distinguish and illustrate covalent and coordination bonds
- identify and predict the geometry of metal complexes
- assign oxidation states to ligands and metal ions
- apply the hard-soft-acid-base principle and chelate effects to determine relative product stability
- predict the magnetic behaviour and stability of complexes and their crystal field stabilisation energy

Indicative Module Content:

* Fundamentals of atomic structure and form of the periodic table.
* Bonding and molecular orbital theory for diatomics.
* General properties of the transition metals as elements and ions.
* Ligands and bonding to metals.
* Formation and stability of metal-ligand complexes
* Chelation and macrocyclic effects.
* Naming complexes.
* Molecular symmetry and point groups.
* Crystal field theory: fundamentals, applications and limitations.

Student Effort Hours:
Student Effort Type Hours
Lectures

24
Tutorial

4
Laboratories

24
Autonomous Student Learning

70
Total

122

Approaches to Teaching and Learning:
The material is presented in lectures, which is reinforced by small-group tutorials and practice question sheets. Students will undertake autonomous learning to expand upon the themes and topics covered, using appropriate textbooks and online resources. Material learnt in the lectures will be underpin the laboratory practical sessions, where students will undertake the synthesis and characterisation of ligands and transition metal complexes, accompanied by analytical determination experiments.

Requirements, Exclusions and Recommendations

Not applicable to this module.


Module Requisites and Incompatibles
Not applicable to this module.
 

Assessment Strategy  
Description Timing Component Scale Must Pass Component % of Final Grade In Module Component Repeat Offered
Exam (Online): An in-person online Brightspace exam held on campus. Students will undertake the exam on their own devices. Students will have access to their lecture notes on Brightspace. End of trimester
Duration:
2 hr(s)
 Graded No

55

 No
Practical Skills Assessment: 7 lab experiments and report submissions. Report submission is 9 pm of the day after the lab session. Week 2, Week 4, Week 5, Week 6, Week 7, Week 8, Week 9 Graded No

30

 No
Quizzes/Short Exercises: Four tutorials - an at-home Brightspace quiz followed by an in-person session with a tutor. The weeks indicated here are the weeks of the in-person session - the quiz will be set the previous week Week 5, Week 7, Week 9, Week 12 Graded No

15

 No

Carry forward of passed components
Yes
 

Resit In Terminal Exam
Autumn Yes - 2 Hour
Please see Student Jargon Buster for more information about remediation types and timing. 

Feedback Strategy/Strategies

• Feedback individually to students, post-assessment
• Group/class feedback, post-assessment
• Online automated feedback

How will my Feedback be Delivered?

Students will receive feedback on tutorials and lab reports through the semester. Question sheets used during the course are worked through in detail towards the end of the course ahead of the exam.

Name Role
Dr Tom Hooper Lecturer / Co-Lecturer
Professor James Sullivan Lecturer / Co-Lecturer
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